Evo Morales has left Bolivia for Mexico, which has granted him political asylum, as the armed forces agreed to help police curb violence that has erupted after the president's stunning resignation left a power vacuum.
The senator set to succeed Morales as interim president, Jeanine Anez, pledged to call fresh elections to end the political crisis.
The United Nations and the Organisation of American States (OAS) earlier voiced fears of a breakdown in security in a country that appeared increasingly rudderless after dozens of officials and ministers resigned along with Morales, some seeking refuge in foreign embassies.
Morales called Mexico's Foreign Minister Marcelo Ebrard on Monday to request asylum and later tweeted that he was "heading to Mexico."